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She won an MTV Award for Best Movie Villain for her part in Kill Bill.
Subsequently, Liu appeared on several episodes of Joey with Matt Le Blanc, who played her love interest in the Charlie's Angels films.
She also had minor roles as Kitty Baxter in the film Chicago and as a psychologist opposite Keira Knightley in the thriller Domino.
In Lucky Number Slevin, she played the leading love interest to Josh Hartnett.
In 2008, she produced and narrated the short film The Road to Traffik, about the Cambodian author and human rights advocate Somaly Mam.
Liu also made a cameo appearance on Futurama (as herself and robot duplicates) in the episodes "I Dated a Robot" and "Love and Rocket", and on The Simpsons in the season 16 episode "Goo Goo Gai Pan".
In 2002, Liu played Rita Foster in Vincenzo Natali's Brainstorm (a k a Cypher).
In 1996, Liu landed her first role in the main cast of a television series, that of Amy Li in Pearl alongside Rhea Perlman and Malcolm Mc Dowell.
Shortly after the end of Pearl's run in 1997, Liu was cast in a role on Ally Mc Beal.